The Pirate and the Professor — Michelle L. Levigne

As civilization crumbles, Kiryn realizes the only way to protect her planet from pirates is to become one. She takes up the mantle of her father, a reformed pirate who saved his homeworld. As captain of the legendary pirate ship, Nova Vendetta, she makes her homeworld a haven for the downtrodden. When the scholarly representative of a neglected colony comes as a peace envoy and makes her think of more than just surviving. When the two of them are shot down in the badlands of her planet, they become partners to survive, then friends, then maybe something more.