Buy: Valiant: Zeroes & Origins, Volume 1 by James Asmus

Paperback editions:

At last ― the essential origins and early adventures of Valiant's most powerful heroes and allies, collected between two covers for the first time anywhere!
Celebrate 25 years of the largest independent superhero universe in comics with these all-star explorations of Valiant's indelible comics book icons, including X-O Manowar, Harbinger, Bloodshot, Archer & Armstrong, Shadowman, and many more! Who they are, how they came to be, and what they fear the most! This is your essential one-stop guide to the biggest heroes, villains, and super-teams that the Valiant Universe has to offer, just in time for Valiant's 25th Anniversary Celebration!
Collecting Archer & Armstrong #0, Bloodshot #0, Harbinger #0, Punk Mambo #0, Quantum and Woody: The Goat #0, Shadowman #0, Unity #0, X-O Manowar #0, and material from Archer & Armstrong #25, Bloodshot #25, Harbinger #25, X-O Manowar #25, and FCBD 2014: Valiant Universe Handbook #1.

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